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Neutralisation and salt formation – basic principles

How it works

In neutralisation, an acidic and a basic solution react with each other. In the simple school model for acids and alkalis, H+-ions (or oxonium ions) from the acidic solution react with OH--ions from the basic solution to form water. The remaining ions form a salt, for example sodium chloride from hydrochloric acid and sodium hydroxide solution. Neutralisation reactions are exothermic. Depending on the substances used and the ratio of amounts, the solution afterwards can be neutral, acidic or basic. In reactions of acids with carbonates or hydrogencarbonates, carbon dioxide can additionally be produced.

Note
Simplified, the following applies to the neutralisation of acidic solutions with alkalis: H+ + OH- → H2O. The remaining ions form the salt. Only with a suitable ratio of amounts is the solution afterwards neither acidic nor basic.

An example

Which products are formed during the neutralisation of hydrochloric acid (HCl) with sodium hydroxide solution (NaOH)?

Water (H2O) and sodium chloride (NaCl) are formed, because the acidic H+-ions react with the OH--ions of the sodium hydroxide solution to form water and the remaining ions Na+ and Cl- form the salt sodium chloride.

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